High-Tg porous polyimide films with low dielectric constant derived from spiro-(adamantane-2,9′(2′,7′-diamino)-fluorene)

Porous polyimide (PI) films with low dielectric constants and excellent thermal properties have been a pressing demand for the next generation of high-performance, miniature, and ultrathin microelectronic devices. A series of novel porous PI films containing fluorenyl-adamantane groups were prepared successfully via thermolysis of poly(ethylene glycol) (PEG) added in the PI matrix. The cross-sectional morphologies of porous PI films showed closed pores with diameters ranging from 135 to 158 nm, which were uniform and regular in shape without interconnectivity. These porous PI films exhibited excellent thermal properties with a glass-transition temperature at 376 °C whereas the 5% weight loss temperature in air excess of 405 °C due to enhanced rigidity afforded by fluorenyl-adamantane groups. Accompanied by thermolysis content of PEG increasing from 0 to 20 wt %, the density of porous PI films decreased, and the corresponding porosity grew significantly from 0 to 11.48%. Depending on porosity, the dielectric constant and dielectric loss of porous PI films significantly declined from 2.89 to 2.37 and from 0.050 to 0.021, respectively. These excellent properties benefit the as-prepared porous PI films for application as interlayer dielectrics, integrated circuit chips, or multichip modules in microelectronic fields. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47313.     

炼化装置高压串低压风险分析

结合高压串低压事故,运用保护层风险分析方法进行系统分析,帮助操作人员从保护层管理方面出发,更加直观的分析装置工艺设计与操作中存在的隐患与缺陷,从而更好的防止事故发生。     

高能电子成像研究进展

本文通过蒙特卡罗程序EGS模拟研究了电子束与靶的相互作用，对成像束流光学进行了设计，并对束流匹配对空间分辨的影响、超快分束技术和产生横向均匀束技术等进行了模拟研究。实验验证了高能电子成像能达到μm量级的空间分辨，并可实现厚度、密度分辨及明-暗场成像等特点。同时给出了后续实验及研究计划，希望进一步提高高能电子成像性能并拓宽其应用领域。     

Translation speed measurements of hydrogen,helium, and argon field-reversed configurations in the central cell of a KMAX mirror device

A series of experimental results of field-reversed configurations (FRCs) on a KMAX (Keda Mirror with AXisymmetricity) tandem mirror machine are reported. Single-side FRC translation processes with three different gas species were measured by avalanche photodiodes. Consistent with the theoretical prediction, the measured FRC speeds were inversely proportional to the square root of the ion mass. However, the speeds of the hydrogen FRC increased even in a uniform magnetic field region while the speeds of the helium and argon FRCs decreased. Possible mechanisms are discussed. The speed of the second pass due to the reflection of the mirror fields was found to be ∼1/3 of the first pass speed. The internal magnetic fields were measured for a colliding-merging argon FRC, and the results show that, even for very slowmoving FRCs, merging can occur.     

罩式退火温度对高强IF钢组织及性能的影响

为研究不同退火温度下高强IF钢的组织性能及织构的变化规律,采用温箱式电阻炉加热模拟罩式退火工艺,研究了不同退火温度下高强IF钢210P1冷轧板力学性能;对不同退火温度钢板的r90进行了统计并对其进行显微组织观察;采用X射线衍射仪及热场发射扫描电镜对不同退火温度的罩式退火成品板进行了织构分析。结果表明,在高强IF钢210P1冷轧板的罩式退火过程中,提高退火温度将使晶粒明显长大。随着退火温度的升高,屈服强度及抗拉强度下降,伸长率升高,n值略有上升,板材横向r值增加较明显,有利织构{111}取向密度增加,不利织构{100}取向密度降低。     

Impact of pre-treatment (soaking or germination) on nutrient and anti-nutrient contents,cooking time and acceptability of cooked red dry bean (Phaseolus vulgaris L.) and chickpea (Cicer arietinum L.) grown in Ethiopia

Pulses are processed in diverse ways prior to consumption. Soaking and germination are among the most common traditional, household-level food processing strategies. This study was carried out to determine the effects of soaking, germination, cooking and their combinations on the contents of selected nutrients and anti-nutrients of red dry bean and chickpea. In addition, the effects of pre-treatment on cooking time and the acceptability of dishes prepared from red dry bean and chickpea were determined. The nutrient compositions (zinc, iron and calcium) of most soaked-cooked and germinated-cooked red dry bean and chickpea samples were not significantly different than those of respective controls. However, soaking and germination pre-treatments significantly lowered the phytate and tannin contents of the red dry bean and chickpea samples, with a few exceptions, and overall, polyphenol contents were lower after soaking-cooking than after germination-cooking. Most scores for sensory attributes of bean-based and chickpea-based dishes prepared from soaked or germinated samples were not significantly different than those of the controls. For most red dry bean and chickpea samples, longer germination times yielded superior results in terms of reductions in cooking time, tannin content, and phytate:zinc and phytate:iron molar ratio.     

Preparation and properties of modified graphene oxide incorporated waterborne polyurethane acrylate

In this study, a new modifier (KPG) was prepared by modifying graphene oxide with γ‐glycidoxypropyl trimethoxysilane (KH560) and polydimethylsiloxane (PDMS). KPG was in turn added to aqueous urethane acrylate for the fabrication of waterborne polyurethane polyacrylate emulsion modified with KH560‐PDMS composite (KPG/WPUA). Textural characterizations of the KPG/WPUA coating were achieved via Fourier transform infrared, SEM, TGA and AFM techniques, which revealed that the KPG/WPUA film possessed a smooth surface. The synthesized KPG/WPUA films were tested for mechanical properties, hydrophobicity and acid/water corrosion performance which suggested their highly hydrophobic surface. KPG/WPUA with 0.1% KPG showed a contact angle of 118.35°, 30.35° higher than that of pristine WPUA. The KPG/WPUA film exhibited higher thermal stability, i.e. a 5% weight loss temperature of 305 °C, which was 30 °C higher than that of pristine WPUA film. The Young's modulus and elongation at break of the KPG/WPUA film were 34.1 MPa and 74.88% respectively, which were higher than that of WPUA film. Furthermore, KPG/WPUA films exhibited greater resistance (without obvious blistering and the white spotting phenomenon) to H₂O₂, HCl and water corrosion than pristine WPUA. The superior performance of KPG/WPUA films was attributed to the network chain structure formed upon the introduction of KPG into WPUA. The outstanding performance of KPG/WPUA films in terms of mechanical properties, thermal stability and high resistance to acidic and water corrosion makes them interesting alternative contenders for target applications. © 2019 Society of Chemical Industry     

高低孔爆破处理高陡边坡的技术分析

针对前期规划不当,大宝山露天矿877 m平台高陡边坡局部存在难以采用预裂爆破技术进行处理的情况,决定采用高低孔爆破处理技术。为了解决这一难题,首先分析了高低孔的相对内涵,并对高低孔孔深计算公式进行了简单推导,然后通过公式计算得到了高低孔的孔深。在施工阶段,为了确保低孔的实施效果,两排低孔分区域使用同段别毫秒延时雷管,晚于高孔起爆。实践表明,处理后的平台平整度良好,坡面较为稳定,对高陡边坡采用高低孔爆破处理具有可行性,效果较好,可为类似边坡处理提供新思路。